Titanium (Ti) Pellets Overview
We sell these pellets and pieces by unit weight for evaporation use in deposition processes. These approximate materials prices are published to provide budgetary guidelines. Actual prices can vary and may be higher or lower, as determined by availability and market fluctuations. To speak to someone directly about current pricing, please click here .
Titanium (Ti) General Information
Titanium is a common material found in a myriad of products including watches, drill bits, laptops, and bicycles, just to name a few. In pure form, it is lustrous and silvery-white in appearance. It has a melting point of 1,660°C, a density of 4.5 g/cc, and a vapor pressure of 10-4 Torr at 1,453°C. It is a sturdy material which is easily fabricated when heat is applied. Its strong, lightweight characteristics and excellent corrosion resistance make it ideal for ocean liner hulls, aircraft engines, and designer jewelry. Titanium is biocompatible so it can be found in surgical tools and implants. Titanium is generally evaporated in vacuum for the purposes of wear and decorative, semiconductor, and optical coatings.
Titanium (Ti) Specifications
Material Type | Titanium |
Symbol | Ti |
Atomic Weight | 47.867 |
Atomic Number | 22 |
Color/Appearance | Silvery Metallic |
Thermal Conductivity | 21.9 W/m.K |
Melting Point (°C) | 1,660 |
Coefficient of Thermal Expansion | 8.6 x 10-6/K |
Theoretical Density (g/cc) | 4.5 |
Z Ratio | 0.628 |
E-Beam | Excellent |
Thermal Evaporation Techniques |
Boat: W Crucible: TiC,TiB2-BN |
E-Beam Crucible Liner Material | FABMATE®, Intermetallic |
Temp. (°C) for Given Vap. Press. (Torr) |
10-8: 1,067 10-6: 1,235 10-4: 1,453 |
Comments | Alloys with W/Ta/Mo; evolves gas on first heating. |
Suggested QCM Crystal | Alloy Crystal: 750-1002-G10**** |
**** Suggestion based on previous experience but could vary by process. Contact local KJLC Sales Manager for further information
Empirical Determination of Z-Factor
Unfortunately, Z Factor and Shear Modulus are not readily available for many materials. In this case, the Z-Factor can also be determined empirically using the following method:
- Deposit material until Crystal Life is near 50%, or near the end of life, whichever is sooner.
- Place a new substrate adjacent to the used quartz sensor.
- Set QCM Density to the calibrated value; Tooling to 100%
- Zero thickness
- Deposit approximately 1000 to 5000 A of material on the substrate.
- Use a profilometer or interferometer to measure the actual substrate film thickness.
- Adjust the Z Factor of the instrument until the correct thickness reading is shown.
Another alternative is to change crystals frequently and ignore the error. The graph below shows the % Error in Rate/Thickness from using the wrong Z Factor. For a crystal with 90% life, the error is negligible for even large errors in the programmed versus actual Z Factor.
Thermal Evaporation of Titanium (Ti)
Titanium can be evaporated via electron beam or thermal evaporation. However, e-beam evaporation is preferred. It is important to note that titanium alloys with refractory metals.
A material's evaporation temperature is often regarded as the temperature that is needed for the material's equilibrium vapor pressure to be 1E-2 Torr. At that vapor pressure, the deposition rate on a substrate in a system of "normal" geometry is good or high. For titanium, that temperature is ~1,750°C. Titanium has to melt and "wet" a boat or crucible in order for efficient evaporation to take place. At this temperature, titanium will be liquid and will quickly alloy with a refractory boat, destroying its electrical and mechanical properties. The end result is the boat typically cracks and falls apart. Despite this, we have had limited success thermally evaporating titanium from a thin width, thick gauge, high current tungsten boat such as our EVS20A015W.
Using a new EVS20A015W, we were able to complete three short runs of about 2,000 angstroms per run with rates between 3-5 angstroms per second. Rates above 10 angstroms per second were possible. We used six 1/8" X 1/8" pellets in each run. The boats will only last for one or two complete evaporation runs at 2,000 angstroms per run. However, these boats are relatively inexpensive when compared to a box heater and crucible setup.
E-beam Evaporation of Titanium (Ti)
Titanium is rated "excellent" for e-beam evaporation. We recommend using a crucible liner as opposed to running the material directly from the copper hearth. Like with thermal evaporation, intermetallic crucibles work well with titanium due to the crucible liner material's unique lubricious and conductive properties. graphite or FABMATE® crucible liners are available as an alternative to the intermetallic crucible liners. Graphite and FABMATE® liners tend to be less expensive than their intermetallic counterparts. However, we have found that power levels have been more stable with the intermetallic liners. More consistent results are achieved when pre-melting titanium, as the material will wet the crucible allowing for efficient evaporation to take place.
A key process note is to consider the fill volume in the e-beam application because we find that the melt level of a material in a crucible directly affects the success of the crucible liner. Overfilling the crucible will cause the material to spill over and create an electrical short between the liner and the hearth. The outcome is cracking in the crucible. This is the most common cause of crucible liner failure. Placing too little material in the crucible or allowing the melt level to get too low can be detrimental to the process as well. When the melt level is below 30%, the e-beam is likely to strike the bottom or walls of the crucible which immediately results in breakage. Our recommendation is to fill the crucible between 2/3 and 3/4 full to prevent these difficulties.
Crucible liners should be stored in a cool, dry place and always handled with gloves or forceps.
See highlighted results that match your result in the table below.
Ordering Table
Material | Description | Size | Quantity | Purity | Notes | Part Number | Price | In Stock | Add To Cart | |
---|---|---|---|---|---|---|---|---|---|---|
Material | Description | Size | Quantity | Purity | Notes | Part Number | Price | In Stock | Add To Cart | |
Titanium |
TITANIUM PELLETS, |
1/2" Dia. x 1/2" Length | Per Gram | 99.90% | EVMTI30HXHX | $1.02 | ||||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/2" Length | 1 lb. | 99.995% | — | EVMTI45QXH | $617.00 | |||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/4" Length | 1 lb. | 99.995% | — | EVMTI45QXQ | $638.00 | |||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/4" Length | 25 g | 99.995% | — | EVMTI45QXQA | $57.00 | |||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/4" Length | 50 g | 99.995% | — | EVMTI45QXQB | $98.00 | |||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/4" Length | 100 g | 99.995% | — | EVMTI45QXQD | $178.00 | |||
Titanium |
TITANIUM PELLETS, |
1/4" Dia. x 1/4" Length | 225 g | 99.995% | — | EVMTI45QXQI | $332.00 | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/4" Length | 1 lb. | 99.995% | — | EVMTI45EXQ | P.O.R. | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/8" Length | 1 lb. | 99.995% | — | EVMTI45EXE | $978.00 | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/8" Length | 25 g | 99.995% | — | EVMTI45EXE-A | $78.00 | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/8" Length | 50 g | 99.995% | — | EVMTI45EXE-B | $139.00 | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/8" Length | 100 g | 99.995% | — | EVMTI45EXE-D | $255.00 | |||
Titanium |
TITANIUM PELLETS, |
1/8" Dia. x 1/8" Length | 250 g | 99.995% | — | EVMTI45EXE-J | $603.00 |
Starter Sources Table
Starter sources can be used in place of pellets for e-beam evaporation. These sources are pre-machined or pre-melted slugs that can be used in conjunction with either a crucible liner or placed directly in the copper hearth of an e-gun. Once the starter source begins to deplete, they can be topped off with additional pellets. The main benefits of starters sources are superior packing density and ease of use. In order to quote a starter source, please contact us by clicking here with your e-gun manufacturer and pocket size.
Description | Material Symbol | Purity | TOD (in) | Height (in) | BOD (in) | Notes | Part Number | Price | In Stock | Add To Cart | |
---|---|---|---|---|---|---|---|---|---|---|---|
Description | Material Symbol | Purity | TOD (in) | Height (in) | BOD (in) | Notes | Part Number | Price | In Stock | Add To Cart | |
TITANIUM STARTER SOURCE, Ti, 99.995% PURE, 1.77" TOD X 1.47" BOD X 0.605" HIGH, +/-0.010" ALL | Ti | 99.995% | 1.770 | 0.605 | 1.470 | EVMTI45.605 | $148.00 |